Tenth Grade · Science · week 17

Naming and writing formulas for ionic compounds

Name binary and polyatomic ionic compounds, including those with variable-charge transition metals, and write correct formulas from a compound's name.

Naming a binary ionic compound (two elements) is straightforward: state the metal's name unchanged, then change the nonmetal's ending to "-ide." NaCl is sodium chloride; MgO is magnesium oxide; Al2O3 is aluminum oxide. Notice the subscripts themselves are never spoken in the name -- "aluminum oxide" says nothing about the 2-to-3 ratio, because that ratio is already forced by the charges once you know the elements involved.

Many transition metals can form more than one possible charge (iron can be Fe2+ or Fe3+, for example), so a Roman numeral in parentheses is added right after the metal's name to specify which charge is meant in that particular compound: FeCl2 is iron(II) chloride (the 2 chlorides, each -1, mean iron must be +2 to balance), while FeCl3 is iron(III) chloride (3 chlorides require iron to be +3).

Polyatomic ions are groups of atoms that carry an overall charge and stay together as a single unit through a reaction -- a short list is worth memorizing: nitrate (NO3-), sulfate (SO4 2-), carbonate (CO3 2-), phosphate (PO4 3-), hydroxide (OH-), and ammonium (NH4+, the one common positive polyatomic ion). Ca(NO3)2 is calcium nitrate (parentheses around NO3 show that the entire polyatomic ion is doubled to balance calcium's +2 charge). To write a formula from a name, use the crisscross method: the cation's charge number becomes the anion's subscript, and the anion's charge number becomes the cation's subscript, then simplify to the lowest ratio if possible.

📋 For the teacher
Teach it (10–15 min):
  • Make (or find) a simple reference card listing the handful of common polyatomic ions with their charges -- nitrate, sulfate, carbonate, phosphate, hydroxide, ammonium -- and keep it in view during every practice session this week; fluency with this short list unlocks a huge fraction of real-world chemical names.
  • Walk through the crisscross method as "the charge you SEE becomes the subscript you WRITE, on the other ion" -- said that way a few times, it becomes close to automatic.
  • For transition metals, anchor the Roman numeral idea to "work backward from what you already know" -- since the nonmetal's charge is fixed and known, the metal's charge is just whatever makes the total zero.
  • Check bottles and boxes around the house together for chemical names on ingredient labels (calcium carbonate in an antacid, sodium bicarbonate for baking soda) as a fun, real-world scavenger hunt for this week's skill.
Talk about it:
  • How do you know when a Roman numeral is needed in an ionic compound's name?
  • What does the crisscross method actually accomplish?
  • Why do parentheses sometimes appear around a polyatomic ion in a formula?

Mastery looks like: They correctly name binary and polyatomic ionic compounds (including variable-charge metals) and correctly write formulas from names using the crisscross method.

Common stumbles: Forgetting the Roman numeral for a variable-charge transition metal; forgetting to reduce a crisscrossed formula to its lowest ratio when the numbers share a common factor.

Homework for this lessonType it, write it with a stylus, or print it for pencil & paper.open →
Records attendance + 15 min of Science for this learner.
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